Clara Santato1 Martin Barbosa1 Marcelo Orlandi2

1, Ecole Polytechnique de Montreal, Montreal, Quebec, Canada
2, UNESP, Araraquara, , Brazil

Electrolyte-gated transistors hold promise for applications in printable and flexible electronics. Metal oxide semiconductors are particularly interesting as electrolyte-gated channel materials for their abundance, thermodynamic stability and ease of process in ambient conditions.
In this work, we synthesized by sol-gel and hydrothermal methods different types of tungsten oxide to be used as channel materials in ion gel-gated transistors. X-ray diffraction and scanning and transmission electron microscopy revealed that the differently processed oxides show a different structure (hexagonal and monoclinic) and morphology (granular, nanofiber and nanoplate). We studied the electrochemical and transistor properties of the oxides using, as the gating media, two different ion gels prepared from the same ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM]TFSI]), and two different block copolymers.
We propose that, for sufficiently high values of the gate-source bias, the doping results from chemical and electrochemical contributions (the chemical contribution being attributed to the reduction of the oxide by the molecular hydrogen formed by reduction of the acidic proton of the cation of the ionic liquid). Our work sheds light on the complexity of the electrolyte gating phenomenon, to fully exploit its technology potential.