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Matthew Pelton2 3 Jordan Andrews1 Igor Fedin4 Dmitri Talapin3 4 Haixu Leng2 Stephen O'Leary1

2, University of Maryland, Baltimore County, Baltimore, Maryland, United States
3, Argonne National Laboratory, Argonne, Illinois, United States
1, University of British Columbia, Kelowna, British Columbia, Canada
4, University of Chicago, Chicago, Illinois, United States

Nonradiative Auger recombination limits the efficiency with which colloidal semiconductor nanocrystals can emit light when they are subjected to strong excitation, with important implications for the application of the nanocrystals in light-emitting diodes and lasers. This has motivated attempts to engineer the structure of the nanocrystals to minimize Auger rates. Here, we study Auger recombination rates in CdSe/CdS core/shell nanoplatelets, or colloidal quantum wells. Using time-resolved photoluminescence measurements, we show that the rate of biexcitonic Auger recombination has a nonmonotonic dependence on the shell thickness, initially decreasing, reaching a minimum for shells with thickness of 2−4 monolayers, and then increasing with further increases in the shell thickness. This nonmonotonic behavior has not been observed previously for biexcitonic recombination in quantum dots, most likely due to inhomogeneous broadening that is not present for the nanoplatelets.

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