MA02.05.24 : Polymer Single Crystal Dielectrics for Organic Field Effect Transistors

5:00 PM–7:00 PM Apr 4, 2018 (America - Denver)

PCC North, 300 Level, Exhibit Hall C-E

Yuhui Yang1 Hongzheng Chen1 Hanying Li1

1, Zhejiang University, Hangzhou, Zhejiang, China

Single crystal dielectrics are ideal candidates for high-performance organic field effect transistors due to the ordered molecular packing and smooth surface. However, it doesn’t obtain much attention due to the lack of facile preparation methods. Here, solution-grown smooth polymer single crystal with width in tens of microns are obtained and used as the dielectric for the organic field effect transistors (OFETs). The interface between the semiconductor and the polymer single crystal dielectrics are more favorable to the charge carrier transport than spin-coated polymer thin-film dielectrics, exhibiting much higher charge mobility. With 6,13-bis(triisopropylsilylethynyl)-pentacene (TIPS-pentacene) single crystal as semiconductor layer, the average OFET mobility reaches up to 1.70±0.97 cm2V-1s-1 with a highest value of 4.95 cm2V-1s-1. This result demonstrated that structural ordering of the polymer dielectrics is critical to further advance the high-performance OFET devices.