Tobias Weller1 Leonie Deilmann2 Jana Timm1 Tobias Doerr3 Peter Beaucage4 Alexey Cherevan2 Dominik Eder2 Ulrich Wiesner4 Roland Marschall1

1, Justus-Liebig-University Giessen, Giessen, , Germany
2, Technische Universität Wien, Vienna, , Austria
3, INM – Leibniz Institute for New Materials, Saarbruecken, , Germany
4, Cornell University, Ithaca, New York, United States

We have prepared the first crystalline and 3D periodically ordered mesoporous quaternary semiconductor photocatalyst in an evaporation-induced self-assembly assisted soft-templating process. Using lab synthesized triblock-terpolymer poly(isoprene-b-styrene-b-ethylene oxide) (ISO)[1] a highly ordered 3D interconnected alternating gyroid pore morphology was achieved exhibiting near and long-range order, as evidenced by small angle X-ray scattering, physisorption, and electron microscopy, with mesopores larger than 40 ±10 nm and a surface area of 37 m2 g-1. Moreover, we revealed the formation process on the phase-pure construction of the material’s pore-walls with its high crystallinity, which proceeds along a highly stable W5+ compound, by both in-situ and ex-situ analyses, including X-ray powder diffraction, infrared spectroscopy, and electron paramagnetic resonance. The resulting photocatalyst CsTaWO6 with its optimum balance between surface area and ordered mesoporosity ultimately shows superior hydrogen evolution rates over its non-ordered reference in photocatalytic hydrogen production. This work will help to pioneer new self-assembly preparation pathways towards multi-element multifunctional compounds for different applications, including improved battery and sensor electrode materials.

[1] M. Stefik, S. Wang, R. Hovden, H. Sai, M. W. Tate, D. Muller, U. Steiner, S. M. Gruner, U. Wiesner, J. Mater. Chem. 2012, 22 (3), 1078–1087.