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Peter Sherrell1 Maria Sokolikova1 Pawel Palczynski1 Francesco Reale1 Federico Pesci1 Cecilia Mattevi1

1, Imperial College London, London, , United Kingdom

Solar electrochemical energy conversion devices including dye-sensitized solar cells and photoelectrochemical (PEC) water splitting systems are crucial tools to mitigate the future environmental impact from fossil fuel consumption. In PEC systems, composed of a cathode performing the hydrogen evolution reaction (HER), and a photoanode where oxygen is evolved, the water-oxidation reaction requires significantly more energy (four electron-hole pairs compared to two), and hence is more challenging compared to the HER [1].
2D layered materials, including transition metal dichalcogenides, are of great interest for opto-electronic devices due to their layer dependant electronic properties. Recent theoretical work has shown that both MoS2 and WS2 at mono-layer have the potential to function as a photoanode for water oxidation [2]. Experimentally, we have recently realized this in the form of thin films of chemically exfoliated MoS2/WS2 heterojunctions for water oxidation, which demonstrate a synergistic effect beyond either individual components performance. This effect arises from efficient charge transfer between the two van der Waals stacked components leading to electron-hole separation and increased reaction time at the surface [3]. Whilst these heterostructures are excellent as proof-of-concept devices, the photocurrents and incident photon-to-current efficiency values are quite low compared to state-of-the-art materials.
Here, we present a high crystal quality MoS2/WS2 heterostructures [4] grown by chemical vapour deposition for salt water oxidation. These heterostructures demonstrate photocurrents densities up to 0.8 mA/cm2 (at 1-sun, +0.7V vs Ag/AgCl) and IPCE peaking at 1.6% in 3.5% NaCl. This performance is superior to both liquid phase processed heterostructures for water oxidation and WSe2 for photo catalytic hydrogen evolution. These heterostructures can be grown over a cm2 area with a high electrochemically active surface area (100 m2/g) and can be transferred onto a variety of flexible substrates for device specific requirements.
These results pave the way for the use of 2D crystal heterostructures in water splitting devices and provide a viable option for the energetically challenging water oxidation reaction.
References
[1] M. Gratzel, Nature 2001, 414, 338.
[2] J. Kang, S. Tongay, J. Zhou, J. Li, J. Wu, Applied Physics Letters 2013, 102, 012111.
[3] F. M. Pesci, M. S. Sokolikova, C. Grotta, P. C. Sherrell, F. Reale, K. Sharda, N. Ni, P. Palczynski, C. Mattevi, ACS Catalysis 2017, 4990.
[4] P. C. Sherrell, M. S. Sokolikova, P. Palczynski, F. Reale, F. M. Pesci, C. Mattevi, Submitted: 2017.

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